2007-2017年中国沙尘气溶胶的三维分布特征及输送过程

利用最新发布的CALIPSO产品，构建了2007-2017年中国沙尘气溶胶的三维分布，并结合HYSPLIT-4模式和再分析数据，探讨了沙尘的三维输送过程。结果表明：中国的沙尘排放源区主要是塔克拉玛干沙漠和巴丹吉林沙漠，沙尘气溶胶出现频率分别为60%和35%。塔克拉玛干沙漠排放的沙尘主要（50%~70%）停留在源地0~6 000 m高度，少部分向东输送至甘肃和内蒙古；巴丹吉林沙漠排放的沙尘则主要向东输送。中国沙尘排放量在春季最大，向东输送最强；夏季，东亚夏季风限制了沙尘向东输送；秋季，沙尘排放减弱，输送强度和夏季相当；沙尘排放量在冬季最小，输送最弱。夏季，沙尘在输送过程中可被抬升至高度5 000 m以上，春季次之，秋、冬季的沙尘主要在低层大气输送。沙尘在向东输送的过程中被抬升并和当地人为污染物混合变为污染性沙尘，华北地区污染性沙尘出现频率高达30%；输送到海洋的沙尘也会与洋面上（0~3 000 m高度）的海盐气溶胶混合，出现频率约为10%。     

An Early Cretaceous slab window beneath central Tibet,SW China: Evidence from OIB‐like alkaline gabbros in the Duolong area

The geodynamic mechanism of the late Early Cretaceous magmatic flare‐up in the collisional zone between the Lhasa and Qiangtang terranes in Tibet is controversial because of a scarcity of robust evidence. To address this problem, we report geochronological, geochemical and Hf isotopic data for the newly discovered Gufeng gabbros from the Duolong Cu–Au mineral district of the western Bangong–Nujiang Suture Zone (BNSZ). The gabbro samples, dated at 126.3 ± 1.8 Ma, show geochemical similarities to typical ocean island basalt (OIB) and have positive εHf(t) values of +3.3 to +6.9. The gabbros were generated by decompression melting of deep upwelling asthenosphere. This event is best explained by slab break‐off and the resultant development of a slab window beneath central Tibet.     

Extreme Flood Events over the Past 300 Years Inferred from Lake Sedimentary Grain Sizes in the Altay Mountains,Northwestern China

Understanding the temporal variations of extreme floods that occur in response to climate change is essential to anticipate the trends in flood magnitude and frequency in the context of global warming. However, long-term records of paleofloods in arid regions are scarce, thus preventing a thorough understanding of such events. In this study, a reconstruction of paleofloods over the past 300 years was conducted through an analysis of grain sizes from the sediments of Kanas Lake in the Altay Mountains of northwestern China. Results showed that grain parameters and frequency distributions can be used to infer possible abrupt environmental events within the lake sedimentary sequence, and two extreme flood events corresponding to ca. 1736–1765 AD and ca. 1890 AD were further identified based on canonical discriminant analysis(CDA) and coarse percentile versus median grain size(C-M) pattern analysis, both of which occurred during warmer and wetter climate conditions by referring to tree-ring records. These two flood events are also evidenced by lake sedimentary records in the Altay and Tianshan mountains. Furthermore, through a comparison with other records, the flood event from ca. 1736–1765 AD in the study region seems to have occurred in both the arid central Asia and the Alps in Europe, and thus may have been associated with changes in the North Atlantic Oscillation(NAO) index.     

张掖盆地地下水硝酸盐污染与人体健康风险评价

地下水是张掖盆地的重要水资源，其硝酸盐污染尚未得到足够重视。对张掖盆地2004、2015年地下水硝酸盐浓度进行了系统分析，并采用美国环境保护署（USEPA）推荐的健康风险评价模型评估了地下水硝酸盐的健康风险。结果表明：自2004年以来张掖盆地地下水硝酸盐污染日趋严重。2015年硝酸盐浓度最高已达到283.32 mg·L^-1，17.61%的采样点硝酸盐氮浓度超过GB5749-2006《生活饮用水卫生标准》中饮用地下水限量值（20 mg·L^-1）。研究区人群经皮肤接触途径摄入硝酸盐的健康风险在可接受水平，而饮水摄入硝酸盐的健康风险较高，总风险中饮水途径引起健康风险的贡献率占99.40%，远大于皮肤接触途径。儿童经饮水摄入和皮肤接触两种途径的健康风险均显著高于成人，分别为成人的1.544倍和1.039倍。32.39%的采样点地下水硝酸盐对儿童的健康风险超出了可接受水平，14.79%的采样点地下水硝酸盐对成人的健康风险不可接受。甘州区城区、临泽县北部边缘及高台县城区周围硝酸盐浓度最高，这些区域内所有人群都面临硝酸盐引发的高健康风险，其余区域硝酸盐引发的健康风险相对较低。     

Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.     

Geophysical Signature of the Shallow Water Flow in the Deepwater Basin of the Northern South China Sea

Shallow water flow (SWF), a disastrous geohazard in the continental margin, has threatened deepwater drilling operations. Under overpressure conditions, continual flow delivering unconsolidated sands upward in the shallow layer below the seafloor may cause large and long-lasting uncontrolled flows; these flows may lead to control problems and cause well damage and foundation failure. Eruptions from over-pressured sands may result in seafloor craters, mounds, and cracks. Detailed studies of 2D/3D seismic data from a slope basin of the South China Sea (SCS) indicated the potential presence of SWF. It is commonly characterized by lower elastic impedance, a higher Vp/Vs ratio, and a higher Poisson’s ratio than that for the surrounding sediments. Analysis of geological data indicated the SWF zone originated from a deepwater channel system with gas bearing over-pressured fluid flow and a high sedimentation rate. We proposed a fluid flow model for SWF that clearly identifies its stress and pressure changes. The rupture of previous SWF zones caused the fluid flow that occurred in the Baiyun Sag of the northern SCS.     

Walking Access Distance of Metro Passengers and Relationship with Demographic Characteristics: A Case Study of Nanjing Metro

In the metropolises of China, the metro plays an increasingly important role in commuting because of its efficiency, affordability, and cleanliness. This paper attempts to explore the relationship between walking access distance to metro stations and the demographic characteristics of passengers, such as age, monthly income, travel frequency, gender, and travel purpose, as well as the influence of the urban context. Nanjing Metro Line 2 is selected as the case study. By using different methods such as a questionnaire survey, spatial decay function, analysis of covariance (ANOVA), network analysis of routes, and K-means cluster analysis, it is suggested that demographic characteristics have a significant impact on the pedestrian walking distance, with the exception of gender. Furthermore, the paper finds a spatial decay effect in walking access distance, the decay rate of which, however, varies across stations. Terminal stations have a larger pedestrian catchment area than in regular and exchange stations. Moreover, the passengers of Nanjing Metro Line 2 can be classified into six groups according to their demographic characteristics, among which education and occupation are vital indicators in determining their willingness to walk to the stations. Middle-class passengers have a higher dependence on the metro and tend to walk longer than other groups do. This study provides an important reference for planners and transport sectors to optimize land-use and transport infrastructures.     

Regional Characteristics and Causes of Haze Events in Northeast China

Northeast China experiences severe atmospheric pollution, with an increasing occurrence of heavy haze episodes. However, the underlying forces driving haze formation during different seasons are poorly understood. In this study, we explored the spatio-temporal characteristics and causes of haze events in Northeast China by combining a range of data sources(i.e., ground monitoring, satellite-based products, and meteorological products). It was found that the ‘Shenyang-Changchun-Harbin(SCH)'city belt was the most polluted area in the region on an annual scale. The spatial distribution of air quality index(AQI) values had a clear seasonality, with the worst pollution occurring in winter, an approximately oval-shaped polluted area around western Jilin Province in spring, and the best air quality occurring in summer and most of the autumn. The three periods that typically experienced intense haze events were Period I from mid-October to mid-November(i.e., late autumn and early winter), Period II from late-December to February(i.e., the coldest time in winter), and Period III from April to mid-May(i.e., spring). During Period I, strong PM_(2.5) emissions from seasonal crop residue burning and coal burning for winter heating were the dominant reasons for the occurrence of extreme haze events(AQI 300). Period II had frequent heavy haze events(200 AQI 300) in the coldest months of January and February, which were due to high PM_(2.5) emissions from coal burning and vehicle fuel consumption, a lower atmospheric boundary layer, and stagnant atmospheric conditions. Haze events in Period III, with high PM_(10) concentrations, were primarily caused by the regional transportation of windblown dust from degraded grassland in central Inner Mongolia and bare soil in western Jilin Province. Local agricultural tilling could also release PM_(10) and enhance the levels of windblown dust from tilled soil. Better control of coal burning, fuel consumption, and crop residue burning in winter and autumn is urgently needed to address the haze problem in Northeast China.     

On the electron density diagnostics of silicon <Emphasis Type="SmallCaps">viii</Emphasis> ion in solar transition region

The conditions for accurate electron density diagnostics in the solar transition region are discussed, and result shows that lines from Si?viii can provide an excellent tool for electron density diagnostics of the emitting plasma. For the Si?viii 1440.50 Å and 1445.75 Å lines, the principle of the electron density diagnostics is discussed for any intensity ratio. By the observed intensity ratio, the diagnostic results of the electron density for the quiet sun and the active region are calculated, and results indicate that in the quiet sun, the averaged electron density is \(\log (N_{e}) = 8.63\); while in the active region, the averaged density gets the maximum \(\log (N_{e}) = 8.86\) in the active region (B), and gets the minimum \(\log (N_{e}) = 8.38\) in the active region (E), where the electron density is in the unit of cm^?3. Finally, the relationship of intensity ratio and electron density is discussed, in the case of lower and higher electron density limits. This discussion is significant in the electron density diagnostics, which will be important for study on coronal heating and acceleration of solar wind.     

广西土壤有机质空间变异特征及其影响因素研究

基于广西第二次土壤普查的270个土壤剖面资料,结合1∶50万数字化土壤类型图、土地利用类型图和气象监测数据等资料,利用地统计学和逐步回归分析等方法对广西表层土壤有机质空间变异特征及其影响因素进行了探究。结果表明：广西表层土壤有机质平均含量为3.11±2.19%,变异系数为70.72%,空间分布呈北高南低的趋势。广西表层土壤有机质空间分布受到自然和人为因素的共同影响,土壤类型、成土母质、海拔、土地利用、气候和坡度6个环境因子对全区土壤有机质含量变异的综合解释能力为47.9%。其中,土壤类型是最重要的影响因素,能独立解释其变异的36.0%,海拔和成土母质分别能独立解释28.5%和15.8%。气温对广西土壤有机质空间分布的影响比降水量更加显著,从而造成了广西土壤有机质整体呈南低北高的趋势。同时,土壤有机质对气温的敏感性在一定程度上受到降雨量的制约。此外,研究区农业耕作管理等因素对土壤有机质的影响也不容忽视。